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In this paper activated neutralized red mud, herein referred to as Toxic-out powder(TOP), is used as a novel adsorbent for removing acetaminophen derived from pharmaceuticals and other personal care products(PPCPs) wastewater. The adsorption of acetaminophen on Toxic-out powder(TOP) is studied as a function of pH, contact time, and adsorbent dosage. The results of adsorption studies indicate that adsorption of acetaminophen by TOP reveals promising results for the removing of acetaminophen in the pharmaceuticals and other personal care products(PPCPs) wastewater, although adsorption of acetaminophen by TOP shows low adsorption capacity at pH values below 7.0 and requires more longer contact time, comparing to activated carbon. It is assumed that adsorption mechanisms of acetaminophen by TOP result in the lattice space of the neoformed minerals such as brucite (Mg(OH)2), aragonite (CaCO3), para-aluminohydrocalcite (CaAl2(CO3)2(OH)4․3H2O), portlandite (Ca(OH)2), hydrocalumite (Ca2Al(OH)7․3H2O) and hydrotalcite (Mg6Al2CO3(OH)16․4H2O) during the TOP manufacturing process. These findings suggest that Toxic-out powder could be used as an efficient low-cost adsorbent for removing acetaminophen in the natural stream, groundwater, and soil as well as pharmaceuticals and other personal care products wastewater.
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참고문헌 (25)
참고문헌 신청
Thomas PM / 2005 / Tracking acidic pharmaceuticals, caffeine, and triclosan through the wastewater treatment process / Environ Toxicol 24(1):25~30
Kumar A / 2010 / Pharmaceuticals, personal care products and endocrine-disrupting chemicals in U.S. surface and finished drinking waters: A proposed ranking system / Sci Total Environ 408(23):5972~5989
Kim SD / 2007 / Vanderford BJ, Snyder SA. Occurrence and removal of pharmaceuticals and endocrine disruptors in South Korean surface, drinking, and waste waters / Water Res 41(5):1013~1021
Huerta-Fontela M / 2011 / Occurrence and removal of pharmaceuticals and hormones through drinking water treatment / Water Res 45(3):1432~1442
Hoegberg LC / 2002 / Effect of ethanol and pH on the adsorption of acetaminophen(paracetamol)to high surface activated charcoal in vitro studies / J. Toxicol Clin Toxicol 40(1):59~67
Kumar A / 2010 / Pharmaceuticals, personal care products and endocrine-disrupting chemicals in U.S. surface and finished drinking waters: A proposed ranking system / Sci Total Environ 408(23):5972~5989
Kim SD / 2007 / Vanderford BJ, Snyder SA. Occurrence and removal of pharmaceuticals and endocrine disruptors in South Korean surface, drinking, and waste waters / Water Res 41(5):1013~1021
Huerta-Fontela M / 2011 / Occurrence and removal of pharmaceuticals and hormones through drinking water treatment / Water Res 45(3):1432~1442
Hoegberg LC / 2002 / Effect of ethanol and pH on the adsorption of acetaminophen(paracetamol)to high surface activated charcoal in vitro studies / J. Toxicol Clin Toxicol 40(1):59~67
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